1D, 2D and 3D liquid crystalline phases formed by bent-core mesogens.
نویسندگان
چکیده
The type of the mesophase is altered by a small change in the molecular architecture, i.e. increasing the number of alkyl chains attached to the mesogenic core at terminal positions. Lamellar (1D) and columnar (2D) phases are formed for molecules with one and three terminal chains, respectively. For those with two chains 3D phases are observed with either cubic or triclinic symmetry structure.
منابع مشابه
Twist grain boundary (TGB) states of chiral liquid crystalline bent-core mesogens.
4-Cyanoresorcinol derived bent-core molecules with a chiral (S)-2-methylbutoxy chain form liquid crystalline phases with TGBA- and TGBC-like structures at the transition from cybotactic nematic via SmA to SmC phases.
متن کاملDark conglomerate phases of azobenzene derived bent-core mesogens - relationships between the molecular structure and mirror symmetry breaking in soft matter.
New 4-bromoresorcinol based bent-core molecules with peripheral fluoro substituted azobenzene wings have been synthesized and the liquid crystalline self-assembly was investigated by differential scanning calorimetry (DSC), optical polarizing microscopy (POM), electro-optic studies and X-ray diffraction (XRD). A new type of optically isotropic mesophase composed of chiral domains with opposite ...
متن کاملHomogeneous and Homeotropic Alignment of Bent-Core Uniaxial and Biaxial Nematic Liquid Crystals
The effect of well-established homeotropically and homogeneously aligning polyimides, developed for calamitic liquid crystals, on the alignment of the nematic phases of bent-core mesogens was investigated using polarizing optical microscopy and conoscopy. Two polyimides, the homogeneously aligning SE7792 and the homeotropically aligning S659, were used to align three bent-core mesogens. Two of ...
متن کاملLaterally substituted symmetric and nonsymmetric salicylideneimine-based bent-core mesogens
Bent-core mesogens have gained considerable importance due to their ability to form new mesophases with unusual properties. Relationships between the chemical structure of bent-core molecules and the type and physical properties of the formed mesophases are relatively unknown in detail and differ strongly from those known for calamitic liquid crystals. In this paper symmetric and nonsymmetric f...
متن کاملDevelopment of polar order and tilt in lamellar liquid crystalline phases of a bent-core mesogen.
A new bent-core mesogen combining a 4-cyanoresorcinol unit with two terephthalate based rod-like wings and terminated by two long alkyl chains, was synthesized and investigated by DSC, XRD, optical, electrooptical and dielectric methods. A series of liquid crystalline phases in the unique sequence SmA-SmA(P)-SmCPR-(M1/SmCPα)-SmCsPA-SmCPA-SmCaPA, mainly distinguished by the degree and mode of co...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 51 24 شماره
صفحات -
تاریخ انتشار 2015